Abstract
In the title compound, [MnCl2(C11H13N5)], the MnII ion is five-coordinated in a distorted square-pyramidal geometry, with three N atoms from the neutral tridentate 2,6-bis(4,5-dihydro-1H-imidazol-2-yl)pyridine ligand and one chloride ion forming the basal plane and the other chloride ion in the apical position. Both dihydroimidazole rings adopt envelope conformations. In the crystal structure, molecules are linked into a three-dimensional network by N—H⋯Cl and C—H⋯Cl hydrogen bonds.
Highlights
In the title compound, [MnCl2(C11H13N5)], the MnII ion is five-coordinated in a distorted square-pyramidal geometry, with three N atoms from the neutral tridentate 2,6-bis(4,5dihydro-1H-imidazol-2-yl)pyridine ligand and one chloride ion forming the basal plane and the other chloride ion in the apical position
Molecules are linked into a three-dimensional network by N—H Cl and C—
Symmetry codes: (i) −x+3/2, y−1/2, −z+1/2; (ii) x−1/2, −y+3/2, z+1/2
Summary
Data collection [2,6-Bis(4,5-dihydro-1H-imidazol-2yl)pyridine]dichloridomanganese(II) Refinement a School of Chemical and Materials Engineering, Jiangnan University, 1800 Lihu Road, Wuxi, Jiangsu Province 214122, People’s Republic of China, and bDepartment of Public Education, Jiangxi Vocational and Technical College of Electricity, 8 Mailu Selected bond lengths (Å). R factor = 0.067; wR factor = 0.187; data-to-parameter ratio = 19.2. In the title compound, [MnCl2(C11H13N5)], the MnII ion is five-coordinated in a distorted square-pyramidal geometry, with three N atoms from the neutral tridentate 2,6-bis(4,5dihydro-1H-imidazol-2-yl)pyridine ligand and one chloride ion forming the basal plane and the other chloride ion in the apical position. Both dihydroimidazole rings adopt envelope conformations. In the crystal structure, molecules are linked into a three-dimensional network by N—H Cl and C— H Cl hydrogen bonds.
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