Abstract
In the title compound, (C12H11N3)[BiCl5]·H2O, the BiIII atom is coordinated by five chloride anions in a distorted square-pyramidal geometry. The planar imidazole ring system [maximum deviation = 0.012 (3) Å] is oriented at a dihedral angle of 6.08 (5)° with respect to the protonated pyridine ring. An O—H⋯Cl interaction links the water molecule to the dianion. In the crystal structure, intermolecular O—H⋯Cl, N—H⋯O and N—H⋯Cl interactions link the molecules into a three-dimensional network.
Highlights
In the title compound, (C12H11N3)[BiCl5]H2O, the BiIII atom is coordinated by five chloride anions in a distorted squarepyramidal geometry
Symmetry codes: (i) −x+1, −y+2, −z+1; (ii) x, −y+3/2, z+1/2; (iii) x−1, y, z; (iv) x, y, z+1
Summary
In the title compound, (C12H11N3)[BiCl5]H2O, the BiIII atom is coordinated by five chloride anions in a distorted squarepyramidal geometry. The planar imidazole ring system [maximum deviation = 0.012 (3) Å] is oriented at a dihedral angle of 6.08 (5) with respect to the protonated pyridine ring. An O—H Cl interaction links the water molecule to the dianion. Intermolecular O—H Cl, N—H O and N—H Cl interactions link the molecules into a three-dimensional network
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