Abstract
AbstractTwo new C12‐ketones, (+)‐(1S, 10R)‐1,10‐dimethylbicyclo[4.4.0]dec‐6‐en‐3‐one (5) and (+)‐(6S, 10S)‐6,10‐dimethylbicyclo[4.4.0]dec‐1‐en‐3‐one (6), have been isolated from Reunion vetiver oil (Vetiveria zizanioides (L.) Nash). Structure and absolute configuration of 5 were established by a four‐step synthesis from (+)‐isonootkatone ((+)‐α‐vetivone) (1). The structure of 6 followed from its spectroscopic properties and was confirmed by direct comparison with an authentic racemic sample. The absolute configuration of 6 was established by chemical correlation with (+)‐α‐eudesmol (13).
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
