Abstract
In the title compound, C24H22N2O2, the central imidazole ring makes dihedral angles of 49.45 (8), 88.94 (9) and 19.43 (8)° with the benzene ring and the two phenyl rings, respectively. The dihedral angle between the phenyl rings is 77.86 (9)°, and they form dihedral angles of 49.06 (9) and 67.31 (8)° with the benzene ring. In the crystal, molecules are linked by O—H⋯N hydrogen bonds, forming chains along the b axis. These chains are connected by C—H⋯O hydrogen bonds, forming a two-dimensional network parallel to (100). In addition, C—H⋯π interactions are also observed. The terminal C and O atoms of the ethanol group are disordered over two sets of sites with an occupancy ratio of 0.801 (5):0.199 (5).
Highlights
The dihedral angle between the phenyl rings is 77.86 (9), and they form dihedral angles of 49.06 (9) and 67.31 (8) with the benzene ring
Molecules are linked by O—
Cg1 is the centroid of the C4–C9 benzene ring
Summary
Shaaban Kamel Mohamed,a,b* Mehmet Akkurt,c* Adel A. Gurbanovf a Chemistry and Environmental Division, Manchester Metropolitan University, Manchester M1 5GD, England, bChemistry Department, Faculty of Science, Minia. University, 61519 El-Minia, Egypt, cDepartment of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, Turkey, dPharmaceutical Chemistry Department, Faculty of Pharmacy, Al Azhar University, Egypt, eMamedaliev Institute of Petrochemical Processes, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan, and fDepartment of Organic Chemistry, Baku State University, Baku, Azerbaijan. Key indicators: single-crystal X-ray study; T = 296 K; mean (C–C) = 0.002 Å; disorder in main residue; R factor = 0.043; wR factor = 0.110; data-to-parameter ratio = 14.2. With the benzene ring and the two phenyl rings, respectively. The dihedral angle between the phenyl rings is 77.86 (9) , and they form dihedral angles of 49.06 (9) and 67.31 (8) with the benzene ring. The terminal C and O atoms of the ethanol group are disordered over two sets of sites with an occupancy ratio of 0.801 (5):0.199 (5)
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