Abstract
AbstractVarious synthetic applications of iron-based Lewis acid complexes are presented through their most noteworthy and groundbreaking applications in asymmetric catalysis. The iron Lewis acids are organized according to their structure, and then their reactivity. It has been reported that various chiral iron Lewis acids can be used in a broad range of synthetic transformations. Diverse categories of chiral ligands are used in asymmetric catalysis using chiral iron complexes, including N,N′-dioxides, bipyridines, oxazolines, Schiff bases, salen/salan-type structures, and aminopyridines.
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