Abstract
In the title compounds, C23H33NO3 and C21H30O3, respectively, the ester linkage in ring A is equatorial. In these steroids, the six-membered rings A and B have chair conformations, but ring C can be better described as a half-chair. The five-membered ring D adopts a 14α-envelop conformation. The A/B, B/C and C/D ring junctions are trans.
Published Version
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