Abstract

The title racemate, C7H10O3, aggregates in the solid as acid-to-ketone hydrogen-bonding catemers [O⋯O = 2.7050 (13) Å and O—H⋯O = 166.1 (17)°] having glide-related components. Four such heterochiral chains, paired centrosymmetrically about (, , ) in the cell, proceed through the cell in the 010 direction, with alignment with respect to the c axis of ++−−.

Highlights

  • The title racemate, C7H10O3, aggregates in the solid as acid-toketone hydrogen-bonding catemers [O O = 2.7050 (13) Å and O—H O = 166.1 (17) ] having glide-related components

  • 010 direction, with alignment with respect to the c axis of HWT is grateful to Professor Gree Loober Spoog for helpful consultations

  • EG and HWT express their gratitude to Sanofi–Aventis for a grant in support of undergraduate research in organic synthesis

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Summary

Structure Reports

Olson Memorial Laboratories, Department of Chemistry, Rutgers University, Newark, NJ 07102, USA. The title racemate, C7H10O3, aggregates in the solid as acid-toketone hydrogen-bonding catemers [O O = 2.7050 (13) Å and O—H O = 166.1 (17) ] having glide-related components. Four such heterochiral chains, paired centrosymmetrically about (12, 12, 12) in the cell, proceed through the cell in the. EG and HWT express their gratitude to Sanofi–Aventis for a grant in support of undergraduate research in organic synthesis. This paper is dedicated to the memory of HWT; he was a dedicated mentor, teacher and friend at Rutgers University-Newark for over 40 years

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Data collection
Graphite monochromator φ and ω scans
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