Abstract
The title compound, [Sn{C6H4(OH)COO}(C6H5)3{OP(C6H5)3}], is comprised of discrete molecules with the SnIVatom in a trigonal–bipyramidal coordination environment. The carboxylate O atom of the salicylate anion and the O atom of the triphenylphosphine oxide moiety are in the axial positions and the threeipsoC atoms occupy the equatorial positions. An intramolecular O—H...O hydrogen bond is present in the anion between the hydroxy group and the carbonyl atom O of the carboxylate group.
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