Abstract
In this study, the bidentate ligand (R)-2-diphenylphosphino-2′-hydroxy-1,1′-binaphthyl (HO-MOP) was investigated as a chiral auxiliary for the asymmetric synthesis of ruthenium polypyridyl complexes. It was found that (R)-HO-MOP serves as an effective chiral auxiliary starting from different precursor complexes, most notably using the commercially available half-sandwich complex [Ru(η6-C6H6)Cl2]2.
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