Abstract
In the title compound, [Pd(C5H4NS)(C18H14PS)(C18H15P)], the PdII atom has a slightly distorted square-planar environment. Two coordination sites are occupied by a P,S-chelating 2-(diphenylphosphanyl)benzenethiolate ligand and the other two by a P atom from a triphenylphosphine ligand and an S atom from a pyridine-2-thiolate ligand, exhibiting a trans arrangement of the two P-donor atoms. In the crystal structure, weak intra- and intermolecular C—H⋯π and π–π interactions are observed. The pyridyl ring is equally disordered over two positions.
Highlights
In the title compound, [Pd(C5H4NS)(C18H14PS)(C18H15P)], the PdII atom has a slightly distorted square-planar environment
Two coordination sites are occupied by a P,S-chelating
The pyridyl ring is disordered over two positions
Summary
In the title compound, [Pd(C5H4NS)(C18H14PS)(C18H15P)], the PdII atom has a slightly distorted square-planar environment. H-atom parameters constrained max = 0.71 e Å 3 For general background to non-symmetric chelating ligands, see: Braunstein & Naud (2001); Dilworth et al (2000); Dilworth & Weatley (2000); Serrano-Becerra et al (2010); Solano-Prado et al (2010).
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