Abstract
In the crystal structure of the title salt, C10H20N3O2+·C24H20B−, the C—N bond lengths in the cation are 1.327 (3), 1.339 (3) and 1.342 (3) Å, indicating partial double-bond character. The central C atom is bonded to the three N atoms, indicating only a slight deviation from a trigonal–planar geometry. The positive charge is delocalized in the CN3plane. The ethoxy group is disordered over two orientations, with an occupancy ratio of 0.60 (1):0.40 (1). C—H...π interactions are present between the guanidinium H atoms and the phenyl C atoms of the tetraphenylborate ions. The phenyl rings form aromatic pockets, in which the cations are embedded. This leads to the formation of a two-dimensional supramolecular pattern along theacplane.
Highlights
In the crystal structure of the title salt, C10H20N3O2+ÁC24H20BÀ, the C—N bond lengths in the cation are 1.327 (3), 1.339 (3) and 1.342 (3) A, indicating partial double-bond character
The ethoxy group is disordered over two orientations, with an occupancy ratio of 0.60 (1):0.40 (1)
C—HÁ Á Á interactions are present between the guanidinium H atoms and the phenyl C atoms of the tetraphenylborate ions
Summary
In the crystal structure of the title salt, C10H20N3O2+ÁC24H20BÀ, the C—N bond lengths in the cation are 1.327 (3), 1.339 (3) and 1.342 (3) A , indicating partial double-bond character. The central C atom is bonded to the three N atoms, indicating only a slight deviation from a trigonal–planar geometry. The positive charge is delocalized in the CN3 plane. C—HÁ Á Á interactions are present between the guanidinium H atoms and the phenyl C atoms of the tetraphenylborate ions. The phenyl rings form aromatic pockets, in which the cations are embedded. This leads to the formation of a two-dimensional supramolecular pattern along the ac plane
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