2-Cycloheptylidene-N-phenylhydrazinecarbothioamide

Mehmet Akkurt,Alaa A Hassan,Joel T Mague,Shaaban K Mohamed,Mustafa R Albayati

doi:10.1107/s1600536814003948

Abstract

In the title compound, C14H19N3S, the seven-membered cycloheptane ring adopts a chair conformation. An intramolecular N—H⋯N hydrogen bond [graph-set motif S(5)] is present in the N—N—C—N chain between the ring systems. An intramolecular C—H⋯S contact also occurs. In the crystal, pairs of molecules form centrosymmetric dimers through N—H⋯S hydrogen bonds [graph-set R 2 2(8)]. These dimers are connected by C—H⋯S interactions with an R 2 2(14) motif.

Highlights

In the title compound, C14H19N3S, the seven-membered cycloheptane ring adopts a chair conformation
Pairs of molecules form centrosymmetric dimers through N—HÁ Á ÁS hydrogen bonds [graph-set R22(8)]. These dimers are connected by C—HÁ Á ÁS interactions with an R22(14) motif
Supporting information for this paper is available from the IUCr electronic archives (Reference: BT6964)

Summary

Structure Reports Online

C14H19N3S, the seven-membered cycloheptane ring adopts a chair conformation. An intramolecular N—HÁ Á ÁN hydrogen bond [graph-set motif S(5)] is present in the N—N—C—N chain between the ring systems. Pairs of molecules form centrosymmetric dimers through N—HÁ Á ÁS hydrogen bonds [graph-set R22(8)]. These dimers are connected by C—HÁ Á ÁS interactions with an R22(14) motif. For general biological properties of thiosemicarbazone scaffold compounds, see: Hu et al (2006); Du et al (2002); Lovejoy & Richardson (2002). For hydrogen-bond motifs, see: Bernstein et al (1995). For ring-puckering parameters, see: Cremer & Pople (1975)

Data collection

DÁ Á ÁA

Special details