Abstract
The coordination of 18-crown-6 to Ce[N(SiMe3)Ph(F)]3 (Ph(F) = pentafluorophenyl) results in a κ(2)-18-crown-6 complex, a unique coordination mode for an f-block cation. The κ(2)-18-crown-6 complex showed exchange with free 18-crown-6 in solution and facile rearrangement of the crown ligand into a κ(6)-18-crown-6 cerium complex.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
