Abstract
Diastereoselective transformations of Leakadine were discovered: dimerization during melting or heating in CHCl 3 with the formation of one diastereomer. The obtained dimer reacts with methyl isocyanate under mild conditions with the formation of an N -methylcarbamoyl derivative – also in the form of one diastereomer. In the diastereoselective reaction of Leakadine with dimethyl formamide dimethyl acetal, 2-dimethylamino-1,3-diazabicyclo[3.1.0]hexan-4-one was obtained. The reaction of Leakadine with perfluoroisobutylene was studied. Authors: R. G. Kostyanovsky, G. K. Kadorkina, O. N. Krutius, and I. I. Chervin. English Translation in Chemistry of Heterocyclic Compounds , 2012, 48 (6), pp 869-874 http://link.springer.com/article/10.1007/s10593-012-1068-1
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