Abstract
The title compound, C6H9N2+·C2H3O2−, contains eight- and sixteen-membered hydrogen-bonded rings involving 2-amino-3-methylpyridinium and acetate ions. The 2-amino-3-methylpyridinium and acetate ions are linked into zigzag chains by C—H⋯O and N—H⋯O hydrogen bonds. The dihedral angle between the 2-amino-3-methylpyridinium ring and the hydrogen-bonded acetate ion is 6.63 (6)°. The heterocycle is fully protonated, enabling amine–imine tautomerization.
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