Abstract

In the title compound, C36H24O6, the benzoyl groups at the 1- and 8-positions of the naphthalene system are in an anti orientation. Both carbonyl groups form intra­molecular O—H⋯O hydrogen bonds with hy­droxy groups affording six-membered rings. The benzene rings of the benzoyl groups make dihedral angles of 59.26 (13) and 59.09 (13)° with the naphthalene ring system. Zigzag C—H⋯O chains and ladder C—H⋯O chains between the phenoxybenzoyl groups along the ab diagonals form an undulating checkered sheet. The molecules are further connected into a three-dimensional network by C—H⋯π interactions.

Highlights

  • C36H24O6, the benzoyl groups at the 1and 8-positions of the naphthalene system are in an anti orientation

  • The molecules are further connected into a three-dimensional network by C—H interactions

  • The authors would like to express their gratitude to Professor Keiichi Noguchi, Instrumentation Analysis Center, Tokyo University of Agriculture and Technology, for his technical advice

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Summary

Data collection

R factor = 0.037; wR factor = 0.096; data-to-parameter ratio = 12.7. C36H24O6, the benzoyl groups at the 1and 8-positions of the naphthalene system are in an anti orientation. H O hydrogen bonds with hydroxy groups affording sixmembered rings. The benzene rings of the benzoyl groups make dihedral angles of 59.26 (13) and 59.09 (13) with the naphthalene ring system. C—H O chains between the phenoxybenzoyl groups along the ab diagonals form an undulating checkered sheet. The molecules are further connected into a three-dimensional network by C—H interactions

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Crystal data
Graphite monochromator
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