Abstract
The asymmetric unit of the crystal structure of the title compound, C14H15NO2S, contains two molecules. The conformations of the N—C bonds in the C—SO2—NH—C segments of the structure have trans and gauche torsion angles with the S=O bonds. Furthermore, the torsion angles of the C—SO2—NH—C groups in the two molecules are 46.1 (3) (glide image of molecule 1) and 47.7 (3)° (molecule 2). The ortho-methyl groups in the sulfonyl benzene ring are oriented away from the S=O bonds. The two benzene rings are tilted relative to each other by 67.5 (1) and 72.9 (1)° in the two molecules. N—H⋯O and C—H⋯O hydrogen bonds pack the molecules into one-dimensional chains in different directions, resulting in a two-dimensional network.
Highlights
The asymmetric unit of the crystal structure of the title compound, C14H15NO2S, contains two molecules
N— HÁ Á ÁO and C—HÁ Á ÁO hydrogen bonds pack the molecules into one-dimensional chains in different directions, resulting in a two-dimensional network
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: KJ2115)
Summary
The asymmetric unit of the crystal structure of the title compound, C14H15NO2S, contains two molecules. The conformations of the N—C bonds in the C—SO2—NH—C segments of the structure have trans and gauche torsion angles with the S O bonds. The torsion angles of the C—SO2— NH—C groups in the two molecules are 46.1 (3) (glide image of molecule 1) and 47.7 (3) (molecule 2). The ortho-methyl groups in the sulfonyl benzene ring are oriented away from the S O bonds. The two benzene rings are tilted relative to each other by 67.5 (1) and 72.9 (1) in the two molecules. N— HÁ Á ÁO and C—HÁ Á ÁO hydrogen bonds pack the molecules into one-dimensional chains in different directions, resulting in a two-dimensional network. Related literature For related structures, see: Gelbrich et al (2007); Gowda et al (2008a,b,c); Perlovich et al (2006)
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