Abstract
The title compound, (CH3NBCl)3 or C3H9B3Cl3N3, is the first crystallographically characterized trialkyltrichloroborazine derivative. It crystallizes with two independent molecules in the asymmetric unit. The B3N3 rings are essentially planar, with B—N distances ranging from 1.428 (5) to 1.449 (4) Å, and with B—N—B and N—B—N angles in the ranges 118.4 (3)–119.4 (3) and 120.7 (3)–121.8 (3)°, respectively. The two independent molecules are staggered parallel along [x, 0, 0] and [x, {1 \over 2}, {1 \over 2}], most probably due to the formation of weak intermolecular C—H...Cl hydrogen bonds.
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