Abstract
In the title compound, (C12H11N3)[SbCl5]·H2O, the SbIII centre is surrounded by five Cl atoms and displays a distorted square-pyramidal coordination geometry. The dihedral angle formed by the plane of the imidazole ring system with the pyridine ring is 4.380 (15)°. The crystal structure is stabilized by N—H⋯Cl, O—H⋯Cl and N—H⋯O hydrogen bonds, forming a three-dimensional network.
Highlights
In the title compound, (C12H11N3)[SbCl5]H2O, the SbIII centre is surrounded by five Cl atoms and displays a distorted square-pyramidal coordination geometry
The dihedral angle formed by the plane of the imidazole ring system with the pyridine ring is 4.380 (15)
The crystal structure is stabilized by N—H Cl, O—H Cl and N—H O hydrogen bonds, forming a three-dimensional network
Summary
R factor = 0.028; wR factor = 0.068; data-to-parameter ratio = 17.1. In the title compound, (C12H11N3)[SbCl5]H2O, the SbIII centre is surrounded by five Cl atoms and displays a distorted square-pyramidal coordination geometry. The dihedral angle formed by the plane of the imidazole ring system with the pyridine ring is 4.380 (15). The crystal structure is stabilized by N—H Cl, O—H Cl and N—H O hydrogen bonds, forming a three-dimensional network
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