2,3-Dimethyl and 2,3,6,7-Tetramethyl Derivatives of Anthra[1,9-cd:4,10-c′d′]bis[1,2]dichalcogenoles as New Electron Donors

Kazuo Takimiya,Hisakazu Miyamoto,Tetsuo Otsubo,Yoshio Aso,Fumio Ogura

doi:10.1246/cl.1990.567

2,3-Dimethyl and 2,3,6,7-Tetramethyl Derivatives of Anthra[1,9-cd:4,10-c′d′]bis[1,2]dichalcogenoles as New Electron Donors

Kazuo Takimiya, Hisakazu Miyamoto + Show 3 more

https://doi.org/10.1246/cl.1990.567

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Journal: Chemistry Letters	Publication Date: Apr 1, 1990
Citations: 9

Affiliation: Hiroshima University

#Donor Character #Charge Transfer Complexes + Show 7 more

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Abstract

Abstract The title compounds involving all chalcogen heterecycles of sulfur, selenium, and tellurium were synthesized as new electron donors, in which the introduced methyl groups served to improve not only the donor character but also the solubility. They with TCNQ, DMTCNQ, or TCNQF4 formed various charge–transfer complexes, some of which were electrically high-conductive.

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