Abstract
In the title molecule, C16H22S8O2, two S atoms, two O atoms and ten C atoms form a 14-membered ring with a boat conformation. In the crystal, C—H⋯O hydrogen bonds link the molecules into dimers which are further connected into a chain along the a axis by C—H⋯S hydrogen bonds.
Highlights
In the title molecule, C16H22S8O2, two S atoms, two O atoms and ten C atoms form a 14-membered ring with a boat conformation
C—HÁ Á ÁO hydrogen bonds link the molecules into dimers which are further connected into a chain along the a axis by C—HÁ Á ÁS hydrogen bonds
Related literature Over the past three decades, chemical groups such as crown ethers have been extensively modified on the tetrathiafulvalene (TTF) skeleton, see: Jeppesen & Becher (2003)
Summary
Key indicators: single-crystal X-ray study; T = 291 K; mean (C–C) = 0.006 A; R factor = 0.042; wR factor = 0.128; data-to-parameter ratio = 16.7. C16H22S8O2, two S atoms, two O atoms and ten C atoms form a 14-membered ring with a boat conformation. C—HÁ Á ÁO hydrogen bonds link the molecules into dimers which are further connected into a chain along the a axis by C—HÁ Á ÁS hydrogen bonds. Related literature Over the past three decades, chemical groups such as crown ethers have been extensively modified on the tetrathiafulvalene (TTF) skeleton, see: Jeppesen & Becher (2003). For details of the synthesis, see: Chen et al (2005). See: Hou et al (2009)
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