Abstract
Cation–π-controlled preorientation of (E)-styrylthiazoles was performed in both solution and solid phases. Irradiation of (E)-styrylthiazoles in the presence of HCl produced synHT dimers in good selectivities, while little selectivity was observed without HCl. X-ray structures for the HCl salts of (E)-styrylthiazoles showed a head-to-tail arrangement through cation–π interactions between the two neighboring molecules. Irradiation of these HCl salts produced synHT dimers in excellent yields.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
