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Abstract
In the title salt, C14H17N2 +·Cl−, the central N atom is pyramidal (sum of bond angles = 330.9°) and there is a near orthogonal relationship between the benzene rings [dihedral angle = 89.95 (10)°]. The crystal packing features N—H⋯Cl hydrogen bonds, which lead to a supramolecular undulating ribbon along the a axis comprising edge-shared eight-membered {⋯HNH⋯Cl}2 synthons. The chains are connected into layers in the ab plane by C—H⋯π interactions.
Highlights
In the title salt, C14H17N2+Cl, the central N atom is pyramidal and there is a near orthogonal relationship between the benzene rings [dihedral angle = 89.95 (10) ]
H atoms treated by a mixture of independent and constrained refinement max = 0.45 e Å3
The combined solution was kept in an ice-salt bath while carbon disulfide (0.02 mol, 1.52 g) was added with constant stirring over one hour
Summary
H atoms treated by a mixture of independent and constrained refinement max = 0.45 e Å3. Min = 0.24 e Å3 a Department of Chemistry, Universiti Putra Malaysia, 43400 Serdang, Malaysia, and Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia. Cg1 is the centroid of the C9–C14 phenyl ring. R factor = 0.047; wR factor = 0.129; data-to-parameter ratio = 14.5. C14H17N2+Cl, the central N atom is pyramidal (sum of bond angles = 330.9 ) and there is a near orthogonal relationship between the benzene rings [dihedral angle = 89.95 (10) ]. The crystal packing features N—H Cl hydrogen bonds, which lead to a supramolecular undulating ribbon along the a axis comprising edge-shared eightmembered { HNH Cl}2 synthons. The chains are connected into layers in the ab plane by C—H interactions
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