Abstract

In the title compound, [Cu(C4H8NO3)Cl(C10H8N2)]·H2O, the CuII atom is in a slightly distorted square-pyramidal coordination geometry with the basal plane defined by the two N atoms of the bipyridine ligand and the N and O atoms from the threoninate ion and the apical site occupied by the Cl atom. In the crystal, inter­molecular O—H⋯O, N—H⋯O, O—H⋯Cl, C—H⋯O and C—H⋯Cl inter­actions link the mol­ecules into a three-dimensional network. A π–π inter­action with a centroid–centroid distance of 3.461 (1) Å is also present.

Highlights

  • CuII atom is in a slightly distorted square-pyramidal coordination geometry with the basal plane defined by the two N atoms of the bipyridine ligand and the N and O atoms from the threoninate ion and the apical site occupied by the Cl atom

  • Intermolecular O—H O, N—H O, O—H Cl, C—H O and C—H Cl interactions link the molecules into a three-dimensional network

  • The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry

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Summary

Data collection

A – interaction with a centroid–centroid distance of 3.461 (1) Å is present

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