Abstract

In the title compound, [Pd(C7H3NO4)(C10H8N2)]·H2O, the PdII cation is four-coordinated in a distorted square-planar coordination geometry defined by the two N atoms of the 2,2′-bipyridine ligand, one O atom and one N atom from the pyridine-2,6-dicarboxylate anion. The complex and solvent water molecule are linked by intermolecular hydrogen bonds. In the crystal, the complex molecules are stacked in columns along the a axis.

Highlights

  • In the title compound, [Pd(C7H3NO4)(C10H8N2)]ÁH2O, the PdII cation is fourcoordinated in a distorted square-planar coordination geometry defined by the two N atoms of the 2,20-bipyridine ligand, one O atom and one N atom from the pyridine-2,6-dicarboxylate anion

  • The complex and solvent water molecule are linked by intermolecular hydrogen bonds

  • The central PdII cation is four-coordinated in a distorted squareplanar coordination geometry defined by the N1 and N2 atoms of the bidentate bipy ligand, the O3 and N3 atoms of the di-anionic dipic ligand

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Summary

Kwang Ha*

Keywords: crystal structure; palladium(II) complex; bipyridine; pyridine-2,6-dicarboxylic acid. In the title compound, [Pd(C7H3NO4)(C10H8N2)]ÁH2O, the PdII cation is fourcoordinated in a distorted square-planar coordination geometry defined by the two N atoms of the 2,20-bipyridine ligand, one O atom and one N atom from the pyridine-2,6-dicarboxylate anion. The complex and solvent water molecule are linked by intermolecular hydrogen bonds. In the crystal, the complex molecules are stacked in columns along the a axis.

Structure description
DÁ Á ÁA
Synthesis and crystallization
Data collection Diffractometer Absorption correction
Kwang Ha
Data collection
Special details
Full Text
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