Abstract
In the title complex, [RuCl2(C13H17N3)(C2H6OS)(CO)], the coordination environment around the Ru atom is slightly distorted octahedral. The Cl atoms are mutually trans to the dimethyl sulfoxide ligand and the imidazole carbene C atom, respectively. The carbonyl ligand is located trans to the pyridine N atom.
Highlights
In the title complex, [RuCl2(C13H17N3)(C2H6OS)(CO)], the coordination environment around the Ru atom is slightly distorted octahedral
We have reported the synthesis and characterization of pyridine functionalized Ru(II)-N-heterocyclic carbene (NHC) nitrosyl or carbonyl complexes and their catalytic activity in hydrogen transfer of ketones (Cheng, Sun et al, 2009; Cheng, Xu et al, 2009)
The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry
Summary
R factor = 0.040; wR factor = 0.110; data-to-parameter ratio = 16.5. In the title complex, [RuCl2(C13H17N3)(C2H6OS)(CO)], the coordination environment around the Ru atom is slightly distorted octahedral. The Cl atoms are mutually trans to the dimethyl sulfoxide ligand and the imidazole carbene C atom, respectively. The carbonyl ligand is located trans to the pyridine N atom
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