Abstract
The development of an optically pure monofluoromethylthiolating reagent based on Oppolzer's camphorsultam auxiliary (1S)-(−)-N-monofluoromethylthio-7,7-dichloro-2,10-camphorsultam 1b was described. Reagents 1b reacted with two types of substrates including oxazolone and oxindole derivatives with good to excellent enantioselectivities under mild conditions, thus representing the first available method for us to access monofluoromethylthiolated stereogenic centers.
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