Abstract
The title compound, C 14 H 27 NO 3 Si, obtained in good yield from a three-step sequence of reactions starting from (4S,SR)-4-(tert-butyldimethylsilyloxy)-3,4-dihydro-5-[(p-tolylsulfinyl)methyl]-2H-pyrrole, serves as a key intermediate in a study of the total synthesis of (+)-castanospermine. The six-membered lactam ring can be best described as having a distorted envelope conformation.
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