1-(Phenyl-sulfon-yl)benzo[1,2:2',3']thieno[5',4'-b]carbazole.

S Thenmozhi,A Subbiahpandi,V Dhayalan,A K Mohanakrishnan

doi:10.1107/s1600536810010044

S Thenmozhi, A Subbiahpandi + Show 2 more

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https://doi.org/10.1107/s1600536810010044

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Abstract

In the title compound, C24H15NO2S2, the ring system composed of the five fused rings is almost planar (r.m.s. deviation for all non-H atoms = 0.056 Å). The dihedral angle between the fused ring system and the phenyl ring is 83.4 (9)°. The crystal packing is stabilized by C—H⋯π and π–π interactions between parallel ring systems [centroid–centroid distances = 3.526 (3), 3.877 (3) and 3.712 (3) Å].

Highlights

Data collectionRefinement a Department of Physics, Presidency College (Autonomous), Chennai 600 005, India, and bDepartment of Organic Chemistry, University of Madras, Guindy Campus, Chennai 600 025, India
In the title compound, C24H15NO2S2, the ring system composed of the five fused rings is almost planar
Cg6 is the centeroid of the C19–C24 ring

Summary

Data collection

Refinement a Department of Physics, Presidency College (Autonomous), Chennai 600 005, India, and bDepartment of Organic Chemistry, University of Madras, Guindy Campus, Chennai 600 025, India. R factor = 0.057; wR factor = 0.192; data-to-parameter ratio = 24.5. Cg6 is the centeroid of the C19–C24 ring. C24H15NO2S2, the ring system composed of the five fused rings is almost planar (r.m.s. deviation for all non-H atoms = 0.056 Å). The dihedral angle between the fused ring system and the phenyl ring is 83.4 (9). The crystal packing is stabilized by C—H and – interactions between parallel ring systems [centroid–centroid distances = 3.526 (3), 3.877 (3) and 3.712 (3) Å]

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Crystal data

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