Abstract
There are two independent molecules in the asymmetric unit of the title compound, C19H24S2. In both molecules, the aliphatic segment of the ligand is in an all-trans conformation: the –S–(CH2)5–S–bridging chain is almost planar (r.m.s. deviation for all non-H atoms = 0.0393 and 0.0796 Å in the two molecules) and maximally extended. Their mean planes form dihedral angles of 4.08 (6)/20.47 (6) and 2.22 (6)/58.19 (6)° with the aromatic rings in the two molecules. The crystal packing is purely governed by weak intermolecular forces.
Highlights
There are two independent molecules in the asymmetric unit of the title compound, C19H24S2
The aliphatic segment of the ligand is in an all-trans conformation: the –S–(CH2)5–S–bridging chain is almost planar (r.m.s. deviation for all non-H atoms = 0.0393 and 0.0796 Ain the two molecules) and maximally extended
For the potential of coordination polymers based on multitopic bridging ligands and metal centers as functional materials, see: Guo et al (2002); Melcer et al (2001)
Summary
There are two independent molecules in the asymmetric unit of the title compound, C19H24S2. In both molecules, the aliphatic segment of the ligand is in an all-trans conformation: the –S–(CH2)5–S–bridging chain is almost planar (r.m.s. deviation for all non-H atoms = 0.0393 and 0.0796 Ain the two molecules) and maximally extended. The aliphatic segment of the ligand is in an all-trans conformation: the –S–(CH2)5–S–bridging chain is almost planar (r.m.s. deviation for all non-H atoms = 0.0393 and 0.0796 Ain the two molecules) and maximally extended Their mean planes form dihedral angles of 4.08 (6)/20.47 (6) and 2.22 (6)/ 58.19 (6) with the aromatic rings in the two molecules. The crystal packing is purely governed by weak intermolecular forces
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