Abstract
The 2′-deoxy-N6-(naphthalen-1-ylmethyl)- (5a) and N6-(pyren-1-ylmethyl)adenosine (5b) were synthesized in two steps from 2′-deoxyadenosine and the adequate arenecarbaldehyde with 1H-benzotriazole as a synthetic auxiliary (Scheme). When the N6-(arylmethyl)-2′-deoxyadenosines were inserted into the junction region of a DNA three-way junction, its thermal stability increased.
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