Abstract
The title compound, C9H15O6N3P2·2H2O, contains two phosphonic acid groups and one benzimidazole group connected by an N(CH2–)3 group. One of the benzimidazole N atoms and two phosphonic acid O atoms of each PO3 group are protonated. Extensive hydrogen-bonding interactions, as well as π–π stacking interactions, are found between the molecules, leading to a three-dimensional supramolecular network structure.
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