Abstract
Alkyl-chain dynamics in the mixed-valent dodecylamine-intercalated vanadium oxide nanosheets (C12VONS) was investigated by means of 400-MHz 1H nuclear magnetic resonance. Two C12VONS samples with distinct alkylammonium-to-alkylamine ratios showed distinct alkyl-chain dynamics, the alkylammonium chains being apparently more disordered than the alkylamine chains. The high-temperature spin–lattice relaxation is dominated by the conformational chain defects and the reorientational motions of the alkyl chains, respectively, in the alkylammonium-abundant system and in the alkylamine-abundant system. The reorientational and conformational changes of the alkyl chains appear to be uncorrelated with the magnetic transitions.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.