Abstract
The longitudinal relaxation timeT1 and the second momentM2 of1H nuclear magnetic resonance line in a wide temperature range have been measured for acetylcholine chloride. Two different types of the methyl groups reorientation occurred. The first type was the hindered rotation of the methyl group denoted as C(1)H3 about the threefold symmetry axis. The second type was the reorientation of the trimethyl group-N(CH3)3 around the pseudo C3′ axis of C(6)-N(7) bond, which accompanied the standard C3 motion of the methyl group. The Dunn-McDowell model was applied to analyze the dynamics observed.
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