Abstract
The methodology of 1H NMR study of the kinetics of the Ni(II) and Zn(II) cations complex formation with 2-aza-5,10,15,20-tetraphenyl-21-carbaporphyrin ([2-N, 21-CH]TPP I) was developed. The processes rate constants are determined using the pseudo-first and pseudo-second order models. It was shown that this methodology allows for identification and evaluation with high accuracy of the effects of donor–acceptor and solvation interactions that occur in the processes of the d-metal cations complex formation with the inverted tetrapyrrole macrocyclic ligands.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
