Abstract

In the title Schiff base, C21H14N4O4, the dihedral angle between the two nitro groups and the central benzene ring are 83.6 (5) and 2.6 (6)°. The anthracene ring system and the benzene ring make a dihedral angle of 0.7 (2)°. Intra­molecular N—H⋯O and C—H⋯N hydrogen bonds occur. In the crystal, C—H⋯O hydrogen bonds link the mol­ecules, forming chains along the b-axis direction.

Highlights

  • Data collectionSobrala and Manuela Ramos Silvab a Chemistry Department, University of Coimbra, P-3004-530 Coimbra, Portugal, and b

  • In the title Schiff base, C21H14N4O4, the dihedral angle between the two nitro groups and the central benzene ring are

  • The title compound was synthesized as part of an investigation of the coordination properties of Schiff bases functioning as ligands

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Summary

Data collection

Sobrala and Manuela Ramos Silvab a Chemistry Department, University of Coimbra, P-3004-530 Coimbra, Portugal, and b. R factor = 0.074; wR factor = 0.242; data-to-parameter ratio = 14.1. In the title Schiff base, C21H14N4O4, the dihedral angle between the two nitro groups and the central benzene ring are. The anthracene ring system and the benzene ring make a dihedral angle of 0.7 (2). N—H O and C—H N hydrogen bonds occur. C—H O hydrogen bonds link the molecules, forming chains along the b-axis direction

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