Abstract
The title compound, C14H11BrN4O4, contains 3-bromophenyl and 2,4-dinitrophenyl groups on opposite sides of a hydrazone unit and crystallizes with two molecules in the asymmetric unit. The dihedral angles between the two ring systems in each molecule are 2.0 (1) and 2.5 (4)°. Weak C—H⋯O hydrogen bonds and weak π–π stacking interactions [centroid–centroid distance = 3.7269 (14) Å] help to establish the packing. Intramolecular N—H⋯O hydrogen bonds are also observed. On one of the rings, the Br atom is disordered over two equivalent positions of the phenyl ring [occupancy ratio 0.8734 (10):0.1266 (10).
Highlights
The title compound, C14H11BrN4O4, contains 3-bromophenyl and 2,4-dinitrophenyl groups on opposite sides of a hydrazone unit and crystallizes with two molecules in the asymmetric unit
The dihedral angles between the two ring systems in each molecule are 2.0 (1) and 2.5 (4)
On one of the rings, the Br atom is disordered over two equivalent positions of the phenyl ring [occupancy ratio
Summary
H. S. Yathirajanb and A. N. Mayekarc a Department of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USA, bDepartment of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore 570 006, India, and cDepartment of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore 570 006, India, and, SeQuent
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