Abstract
A new 1D silver cluster-assembled complex Ag10bpy-CH3CN exhibiting intense photoluminescence was reported. Upon the loss of coordinated acetonitrile, Ag10bpy-CH3CN form Ag10bpy with Ag10S6 cores slightly distorted, being accompanied with photoluminescence quenching. Inverse process can be realized by treating Ag10bpy with acetonitrile and shows a selectively erasable photoluminescent switch.
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