Abstract
Three novel polybromotellurates(IV) were obtained by reactions of TeO2 in conc. HBr with Br2 and tri‐ or tetraalkylammonium salts. They contain [TeBr6]2– octahedra connected by {Br2} linkers into one‐ or pseudo‐two‐dimensional networks. The thermal stability of the products was investigated by TGA; additionally, all compounds were characterized by Raman spectroscopy. Energies of Br···Br interactions were estimated by DFT calculations (QTAIM method).
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