Abstract
Abstract The nitrogen-15 nuclear magnetic resonance spectra of the cobalt(III) complexes containing 15NO2− were first measured; the coordination chemical shifts, Δδ (=δcomplex–δfree), were found to be from 135.0 to 161.5 ppm. The relationship between Δδ and the geometrical configuration was discussed in terms of the paramagnetic anisotropy of the cobalt(III) ion.
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