Abstract

AbstractNitranions of pyrrole, aromatic and heteroaromatic amines, carboxamides and pyridyl carbanions are generated by deprotonation either of NH or CH acids. The positive or negative displacements undergone by the 15N nucleus relative to the neutral precursor depend on whether a σ or π charge is increased. They are associated with the symmetry of the nitrogen orbital in which the electron pair is either generated or that to which it is delocalized.

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