Abstract
Some 1,3-dicarbonyl compounds (such as pentane-2,4-dione and 3-oxo- N-phenylbutanamide) were found to constitute highly efficient, yet low-priced and phosphine-free ligands for the Pd-catalyzed Heck and Suzuki reactions of aryl bromides and iodides with very high turnover numbers (ca. 10 3–10 4).
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