Abstract
The concentration dissociation constants pKc of the α and β D-glucose anomers were measured at pH 12–14 by the 13C NMR method. The pKc values for L ⇔ H−1L + H equilibria at 25°C and an ionic strength of 1.0 mol/l (NaCl) were pKcα = 12.31 ± 0.03 and pKcβ = 12.03 ± 0.01. Dissociation was found to shift all the spectrum lines downfield. The most probable hydroxyl group responsible for the dissociation of β-D-glucose was determined.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
