Abstract
A complete 13C NMR characterization of two linear low-density polyethylenes (LLDPE), one highly branched and the other lowly branched, is presented. These LLDPE were synthesized with a new catalyst: the [η3-methallyl-nickel-dad]PF6 complex by homopolymerization of ethylene, using different experimental conditions. Methyl, ethyl, propyl, butyl, amyl, and long branches were assigned and quantified.
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