Abstract
13C-13C coupling constants for all aldopyranoses of the D-series were calculated in terms of the self-consistent finite perturbation theory. General relations holding in the stereochemical behavior of the 13C-13C coupling constants for the pyranose ring were found. The results obtained make it possible to perform conformational analysis and assign configuration of the anomeric center in molecules of carbohydrates and products of their metabolism, containing a pyranose fragment.
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