Abstract
Abstract Stereoselective glycosylation of several glycosyl acceptors with 2,3,4,6-tetra-O-benzyl-β-d-glucopyranosyl fluoride was successfully carried out in diethyl ether by using a catalytic amount of trifluoromethanesulfonic acid (TfOH) in the coexistence of molecular sieve 5Å (MS5Å) to afford predominantly the corresponding α-linked disaccharides in high yields, which was applied to one-pot sequential syntheses of trisaccharides.
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