Abstract

The asymmetric unit of the title compound, C11H12BrClN2OS, consists of two crystallographically independent mol­ecules. In each mol­ecule, the butano­ylthio­urea unit is nearly planar, with maximum deviations of 0.1292 (19) and 0.3352 (18) Å from the mean plane defined by nine non-H atoms, and is twisted relative to the terminal benzene ring with dihedral angles of 69.26 (7) and 82.41 (7)°. An intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif in each butano­ylthio­urea unit. In the crystal, N—H⋯O hydrogen bonds link the two independent mol­ecules together, forming an R 2 2(12) ring motif. The mol­ecules are further connected into a tape along the c axis via N—H⋯S and C—H⋯S hydrogen bonds.

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