Abstract
The title compound [systematic name: (12R)-4,8-dimethyl-12-[(1′R)-1′,2′,3′,4′-tetrahydro-1′-naphthyl)aminomethyl]-3,14-dioxatricyclo[9.3.0.02,4]tetradec-7-en-13-one}, C25H33NO3, was formed from the reaction of (1R)-1-aminotetralin with parthenolide in methanolic solution. X-ray crystal structure analysis determined that the configuration of the new chiral center in the title compound was R.
Highlights
The title compound [systematic name: (12R)-4,8-dimethyl-12[(10R)-10,20,30,40-tetrahydro-10-naphthyl)aminomethyl]-3,14dioxatricyclo[9.3.0.02,4]tetradec-7-en-13-one}, C25H33NO3, was formed from the reaction of (1R)-1-aminotetralin with parthenolide in methanolic solution
X-ray crystal structure analysis determined that the configuration of the new chiral center in the title compound was R
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: HG2376)
Summary
Key indicators: single-crystal X-ray study; T = 90 K; mean (C–C) = 0.003 A; R factor = 0.043; wR factor = 0.111; data-to-parameter ratio = 14.3. The title compound [systematic name: (12R)-4,8-dimethyl-12[(10R)-10,20,30,40-tetrahydro-10-naphthyl)aminomethyl]-3,14dioxatricyclo[9.3.0.02,4]tetradec-7-en-13-one}, C25H33NO3, was formed from the reaction of (1R)-1-aminotetralin with parthenolide in methanolic solution. X-ray crystal structure analysis determined that the configuration of the new chiral center in the title compound was R. Related literature For related literature, see: Allen et al (1987); Crooks et al (2005); Desiraju & Steiner (1999); Nasim et al (2007a,b)
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