Abstract
Stack 'em up: Two coordination complexes—one a perfluoroarene-functionalized β-diketonate copper complex (purple, see picture), the other an arene-functionalized metal (M=Cu, Pd, Pt) complex (green)—form alternately layered arrays through arene–perfluoroarene interactions with metal-to-metal distances close to van der Waals contacts to give 1:1 cocrystals as one-dimensional metal wires.
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