1-Methyl-N-(4-nitrobenzyl)pyridinium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)nickelate(III)

Abstract

The title compound, (C13H13N2O2)[Ni(C3S5)2], is composed of layers of cations and anions. The NiIII ion is in a planar environment, coordinated by the four S atoms of two dmit2− ligands. There are some weak S⋯S and Ni⋯S interactions, and some non-classical hydrogen bonds (C—H⋯S) are also observed. These interactions generate a three-dimensional framework.